Dr. Emanuel Hupf
Universität Bremen
Fachbereich 2: Biologie/Chemie
Institut für Anorganische Chemie und Kristallographie
Universitätslektor
Leobener Straße 7 — Gebäude NW2 - Raum C2020
28359 Bremen
Büro Tel.: +49 (0)421 218-63161
Publikationen
44
E.A. Chulanova, E.A Radiush, N.A. Semenov, E. Hupf, I.G Irtegova, Y.S Kosenkova, I.Y.Bagryanskaya, L.A Shundrin, J. Beckmann, A.V. Zibarev
Tuning Molecular Electron Affinities against Atomic Electronegativities by Spatial Expansion of a p-System.
Chem.Phys.Chem. 202352,5918-5925
43
F. Feige, L.A. Malaspina, F. Kleemiss, J.F. Kögel, S. Ketkov, E. Hupf,S. Grabowsky, J. Beckmann
An investigation into the Brønsted acidity of the perfluorinated alkoxy silanes {(F3C)3CO}3SiH and {(F6C5)3CO}2Si(Cl)H.
Dalton Trans. 202352,5918-5925
42
P. Komorr, M. Olaru, E. Hupf, S. Mebs, J. Beckmann
Donor Acceptor Complexes between the Chalcogen Fluorides SF2, SeF2, SeF4 and TeF4 and an N-Heterocyclic Carbene.
Chem. Eur. J. 2022, 28,Article number e202201023.
41
D. Duvinage, P. Puylaert, E.K. Wieduwilt, A.L. Malaspina, A. J. Edwards, E. Lork, S. Mebs, E. Hupf, S. Graboswky, J. Beckmann
Nickel and Palladium Complexes of a PP(O)P Pincer Ligand Based upon a peri-Substituted Acenaphthyl Scaffold and a Secondary Phosphine Oxide.
Inorg. Chem. 2022, 61,8406-8418.
40
S. Furan, M. Molkenthin, K. Winkels, E. Lork, S. Mebs, E. Hupf, J. Beckmann
Tris(6-diphenylphosphinoacenaphth-5-yl)gallium: Z-Type Ligand and Transmetalation Reagent.
Organometallics 2021, 40,3785-3796.
39
F. Feige, L.A. Malaspina, E. Rychagova, S. Ketkov, S. Grabowsky, E. Hupf, J. Beckmann
Perfluorinated Trialkoxysilanol with Dramatically Increased Brønsted Acidity.
J. Organomet. Chem. 2021, 27,15898-15902.
38
S. Holsten, A.L. Malaspina, F. Kleemiss, S. Mebs, E. Hupf, S. Grabowsky, Beckmann
Different Reactivities of (5-Ph2P-Ace-6-)2MeSiH toward the Rhodium(I) Chlorides [(C2H4)2RhCl]2and [(CO)2RhCl]2. Hirshfeld Atom Refinement of a Rh-H···Si Interaction.
Organometallics 2021, 40,2027-2038.
37
S. Furan, M. Vogt, K. Winkels, E. Lork, S. Mebs, E. Hupf, J. Beckmann
(6-Diphenylphosphinoacenaphth-5-yl)indium and -nickel Compounds: Synthesis, structure, transmetalation, and cross-coupling reactions.
Z. Anorg. Allg. Chem. 2021, 40,1284-1295.
36
S. Furan, E. Hupf, E. Lork, J. Beckmann
Synthesis and Structure of 5-Diphenylphosphino- acenaphth-6-yl Boronic Acid, Related Dialkyl Esters and Boroxine Rings.
Z. Anorg. Allg. Chem . 2021, 647,507-512.
35
F. Meyer, E. Hupf, E. Lork, S. Grabowsky, S. Mebs, J. Beckmann
Bis(6-diphenylphosphino-acenaphth-5-yl)sulfoxide: A New Ligand for Late Transition Metal Complexes.
Eur. J. Inorg. Chem.2020, 2020, 3829–3836 .
34
S. Furan, E. Lork, S. Mebs, E. Hupf, J. Beckmann
Transmetallation of Bis(6-diphenylphosphinoacenaphth-5-yl)-Mercury and -Tributyltin with Precious Metal Chlorides.
Z. anorg. allg. Chem.2020, 646, 856–865 .
33
S. Furan, E. Hupf, E. Lork, J. Beckmann
Synthesis and structure of 6-diphenylphosphinoacenaphth-5-yl bismuth compounds.
Revue Roumaine de Chimie2020, 65, 673–676 .
32
R.S. Markl, N. Hohn, E. Hupf, L. Bießmann, V. Korstgens, L.P. Kreuzer, G. Mangiapia, M. Pomm, A. Kriele, E. Rivard, P. Muller-Buschbaum
Comparing the backfilling of mesoporous titania thin films with hole conductors of different sizes sharing the same mass density.
IUCrJ2020, 7, 268–275 .
31
S. Holsten, E. Hupf, E. Lork, S. Mebs, J. Beckmann
Proximity enforced oxidative addition of a strong unpolar σ-Si-Si bond at rhodium(i).
Dalt. Trans.2020, 49, 1731–1735 .
30
E. Hupf, F. Kaiser, P.A. Lummis, M.M.D. Roy, R. McDonald, M.J. Ferguson, F.E. Kühn, E. Rivard
Linking Low-Coordinate Ge(II) Centers via Bridging Anionic N-Heterocyclic Olefin Ligands.
Inorg. Chem.2020, 59, 1592–1601 .
29
F. Kleemiss, E.K. Wieduwilt, E. Hupf, M.W. Shi, S.G. Stewart, D. Jayatilaka, M. J. Turner, K, Sugimoto, E. Nishibori, T. Schirmesiter, T.C. Schmidt, B. Engels, S. Grabowsky
Similarities and Differences between Crystal and Enzyme Environmental Effects on the Electron Density of Drug Molecules.
Chem. Eur. J.2020, im Druck, .
28
E. Hupf, L.A. Malaspina, S. Holsten, F. Kleemiss, J. Beckmann, A.J. Edwards; J.R. Price, V. Kozich, K. Heyne, S. Mebs, S. Grabowsky, J. Beckmann
Proximity Enforced Agostic Interactions Involving Closed-Shell Coinage Metal Ions.
Inorg. Chem.2019, 58, 16372–16378.
27
L.A. Malaspina, E.K. Wieduwilt, J. Bergmann, F. Kleemiss, B. Meyer, M.F. Ruiz-López, R. Pal, E. Hupf, J. Beckmann, R.O Piltz, A.J. Edwards, S. Grabowsky, A. Genoni
Fast and Accurate Quantum Crystallography: From Small to Large, from Light to Heavy.
J. Phys. Chem. Lett.2019, 10, 6973–6982.
26
S.M. Parke, S. Tanaka, H. Yu, E. Hupf, M.J. Ferguson,Y. Zhou, K. Naka, E. Rivard
Highly Fluorescent Benzophosphole Oxide Block-Copolymer Micelles.
Macromolecules2019, 52, 7477–7488.
25
E. Hupf, Y. Tsuchiya, W. Moffat, L. Xu, M. Hirai, Y. Zhou, M.J. Ferguson, R. McDonald, T. Murai, G. He, E. Rivard
A Modular Approach to Phosphorescent π-Extended Heteroacenes.
Inorg. Chem.2019, 58, 13323–13336.
24
K. Takahashi, S. Shimo, E. Hupf, J. Ochiai, C.A. Braun, W. Torres Delgado, L. Xu, E. Rivard, N. Iwasawa
Self-Assembly of Macrocyclic Boronic Esters Bearing Tellurophene Moieties and Their Guest-Responsive Phosphorescence.
Chem. Eur. J.2019, 25, 8479–8483.
23
T.G. Do, E. Hupf, E. Lork, J.F. Kögel, F. Mohr, A. Brown, R. Toyoda, R. Sakamoto, H. Nishihara, S. Mebs, J. Beckmann
Aurophilicity and Photoluminescence of (6-Diphenylpnicogenoacenaphth-5-yl)gold Compounds.
Eur. J. Inorg. Chem.2019, 2019, 647–659.
22
T.G. Do, E. Hupf, E. Lork, S. Mebs, J. Beckmann
Bis(6-diphenylphosphinoacenaphth-5-yl)telluride as a ligand toward coinage metal chlorides.
Dalt. Trans.2019, 48, 2635–2645.
21
S. Furan, E. Hupf, J. Boidol, J. Brünig, E. Lork, S. Mebs, J. Beckmann
Transition metal complexes of antimony centered ligands based upon acenaphthyl scaffolds. Coordination non-innocent or not?.
Dalt. Trans.2019, 48, 4504–4513.
20
S.M. Parke, E. Hupf, G.K. Matharu, I. de Aguiar, L. Xu, H. Yu, M.P. Boone, G.L.C. de Souza, R. McDonald, M.J. Ferguson, H. He, A. Brown, E. Rivard
Aerobic Solid State Red Phosphorescence from Benzobismole Monomers and Patternable Self-Assembled Block Copolymers.
Angew. Chem. Int. Ed.2018, 57, 14841-14846.
19
T.G. Do, E. Hupf, E. Lork, J. Beckmann
Bis(6-diphenylphosphinoacenaphth-5-yl)telluride as a ligand toward manganese and rhenium carbonyls.
Molecules2018, 23, 2805.
18
S.M. Parke, M.A.B. Narreto, E. Hupf, R. McDonald, M.J. Ferguson, F.A. Hegmann, E. Rivard
Understanding the origin of phosphorescence in bismoles: A synthetic and computational study.
Inorg. Chem. 2018, 57,7536–7549.
17
M. Olaru, R. Kather, E. Hupf, S. Mebs, J. Beckmann
A Monoaryllead Trichloride That Resists Reductive Elimination.
Angew. Chem. Int. Ed.2018, 57,5917–5920.
16
M. Fugel, D. Jayatilaka, E. Hupf, J. Overgaard, V.R. Hathwar, P. Macchi, M.J Turneer, J.A.K. Howard, O.V. Dolomanov, H. Puschmann, B.B. Iversen, H.-B. Bürgi, S. Grabowsky
Probing the accuracy and precision of Hirshfeld atom refinement with HARt interfaced with Olex2.
IUCrJ2018, 5,32-44.
15
E. Hupf, M. Olaru, C.I. Raţ, M. Fugel, C.B Hübschle, E. Lork, S. Grabowsky, S. Mebs, J. Beckmann
Mapping the Trajectory of Nucleophilic Substitution at Silicon Using a peri-Substituted Acenaphthyl Scaffold.
Chem. Eur. J.2017, 23,10568–10579.
14
S. Furan, E. Hupf, E. Lork, S. Mebs, J. Beckmann
Insights into Frustrated and Regular peri-Substituted (Ace-)Naphthylaminoboranes and (Ace-)Naphthylphosphinoboranes.
Eur. J. Inorg. Chem.2017, 2017,3302–3311.
13
E. Hupf, T.G. Do, A. Nordheider, M. Wehrhahn, P. Sanz Camacho, S.E. Ashbrook, E. Lork, A.M.Z. Slwain, S. Mebs, J.D. Woolins, J. Beckmann
Selective Oxidation and Functionalization of 6-Diphenylphosphinoacenaphthyl-5-tellurenyl Species 6-Ph2P-Ace-5-TeX (X = Mes, Cl, O3SCF3). Various Types of P-E···Te(II,IV) Bonding Situations (E = O, S, Se).
Organometallics2017, 36,1566-1579.
12
E. Hupf, R. Kather, M. Vogt, E. Lork, S. Mebs, J. Beckmann
Role of Dispersion in Metallophilic Hg...M Interactions (M = Cu, Ag, Au) within Coinage Metal Complexes of Bis(6-diphenylphosphinoacenaphth-5-yl)mercury.
Inorg. Chem.2016, 55,11513–11521.
11
T.G. Do, E. Hupf, A. Nordheider, E. Lork, A.M.Z. Slwain, S.G. Makarov, S.Y. Ketkov, S. Mebs, J.D. Woolins, J. Beckmann
Intramolecularly Group 15 Stabilized Aryltellurenyl Halides and Triflates.
Organometallics2015, 34,5341–5360.
10
E. Hupf, E. Lork, S. Mebs, J. Beckmann
Sterically Congested 5-Diphenylphosphinoacenaphth-6-yl-silanes and -silanols.
Organometallics2015, 34,3873–3887.
9
J. Brünig, E. Hupf,E. Lork, S. Mebs, J. Beckmann
A tetranuclear arylstibonic acid with an adamantane type structure.
Dalton. Trans.2015, 44,7105–7108.
8
A. Nordheider, E. Hupf, B.A. Chalmers, F.R Knight, M. Bühl, S. Mebs, L. Checińska, E. Lork, P.S. Camacho, S.E. Ashbrook, K.S. Athukorala Arachchige, D.B. Cordes, A.M.Z. Slawin, J. Beckmann, J.D. Woolins
Peri -substituted phosphorus-tellurium systems-an experimental and theoretical investigation of the p⋯te through-space interaction.
Inorg. Chem.2015, 54,2435–2446.
7
E. Hupf, E. Lork, S. Mebs, J. Beckmann
6-Diphenylphosphinoacenaphth-5-yl-mercurials as Ligands for d10 Metals. Observation of Closed-Shell Interactions of the Type Hg(II)⋯M; M = Hg(II), Ag(I), Au(I).
Inorg. Chem.2015, 54,1847–1859.
6
E. Hupf, E. Lork, S. Mebs, L. Chęcińska, J. Beckmann
Probing donor-acceptor interactions in peri -substituted diphenylphosphinoacenaphthyl-element dichlorides of group 13 and 15 elements.
Organometallics2014, 33,7247-7259.
5
E. Hupf, E. Lork, S. Mebs, J. Beckmann
Intramolecularly coordinated (6-(Diphenylphosphino)acenaphth-5-yl) stannanes. Repulsion vs attraction of P- and Sn-containing substituents in the peri positions.
Organometallics2013, 33,2409-2423
4
J. Beckmann, E. Hupf, E. Lork, S. Mebs
Peri -substituted (Ace)naphthylphosphinoboranes. (Frustrated) Lewis Pairs.
Inorg. Chem.2013, 52,11881-11888
3
J. Beckmann, T.G. Do, S. Grabowsky, E. Hupf, E. Lork, S. Mebs
Peri-interactions in 8-Diphenylphosphino-1-bromonaphthalene, 6-Diphenylphosphino-5-bromoacenaphthene, and derivatives.
Z. anorg. allg. Chem.2013, 639,2233-2249
2
J. Beckmann, E. Hupf, E. Lork
Synthesis of 7,7,14,14-tetrachlorodinaphtho[1,8 bc :1′,8′-fg] [1,5]distannocine. Molecular structure of the di-water tetra-THF adduct.
Main Group Met. Chem.2013, 36,145-149
1
T. Bredtmann, E. Hupf, B. Paulus
Electronic fluxes during large amplitude vibrations of single, double and triple bonds.
Phys. Chem. Chem. Phys.2012, 14,15494-15501